Modeling the Process of Methane Phlegmatization with Thermally Activated Water in an Enclosed Volume of Thermal Power Plants



Annotation:

Preventing methane fires is one of the main challenges of fire safety systems in thermal power plants. The analysis of existing fire prevention systems at energy facilities demonstrated their low efficiency. It has been proposed to consider the use of thermally activated water for methane phlegmatization in case of accidental leakage in the enclosed volume of the energy industry facilities with the application of mathematical modeling.
Based on the calculations, the number of technical devices of supply for non-leak-tight rooms of various degrees has been established. When a certain coefficient of non-leak-tightness is reached, which corresponds with aquatic medium supply in metastable phase state to the open space, the number of trunks will be maximum for a given volume. It is practicable to install supply devices of water medium in metastable phase state on lateral surfaces, whereas phlegmatizing concentrations are achieved within 10 sec from the moment of supply. It has been established that the existing systems of fire prevention are not efficient enough as in some cases these may lead to the occurrence of explosive local areas. A method to prevent combustible gas fires with aquatic medium in a metastable phase state in enclosed volumes of energy facilities has been proposed and theoretically substantiated. The necessary number of technical devices to supply thermally activated water depending on the room volume and non-leak-tightness coefficient have been calculated. Using the software and hardware package Pyrosim has confirmed the correctness of performed calculations and helped to identify the optimal method of supplying aquatic medium in metastable phase state to the volume of the engine room of a thermal power plant.

References:
1. Chistyakov T.I., Roenko V.V., Khramtsov S.P. On the issue of the elimination of chlorine spills in the Arctic zone of the Russian Federation using the aquatic medium technology in the metastable phase state. Grazhdanskaya oborona na strazhe mira i bezopasnosti: materialy 8-y Mezhdunar. nauch.-prakt. konf., posvyashchennoy Vsemirnomu dnyu grazhdanskoy oborony (Civil defense on guard of peace and safety: proceedings of the 8th International Scientific and Practical Conference dedicated to the World Day of civil defense). In 5 parts. Pt. 2. Moscow: Akademiya Gosudarstvennoy protivopozharnoy sluzhby, 2024. pp. 104–109. (In Russ.).
2. Roenko V.V., Khalikov R.V. Fire and explosion safety of enclosed spaces of gas-compressor stations. Pozhary i chrezvychaynye situatsii: predotvrashchenie, likvidatsiya = Fire and Emergencies: Prevention, Elimination. 2020. № 1. pp. 30–35. (In Russ.). DOI: 10.25257/FE.2020.1.30-35
3. Azatyan V.V. Features of the physicochemical mechanisms and kinetic laws of combustion, explosion, and detonation of gases. Kinetika i kataliz = Kinetics and Catalysis. 2020. Vol. 61. № 3. pp. 291–311. (In Russ.). DOI: 10.31857/S0453881120030041
4. Liu H., Wang F. Research on N2-inhibitor-water mist fire prevention and extinguishing technology and equipment in coal mine goaf. PLOS One. 2019. Vol. 14. Iss. 9. pp. 1–21. DOI: 10.1371/journal.pone.0222003
5. Azatyan V.V., Wagner H.-Gg., Vedeshkin G.K., Aivazyan R.G. Suppression of Detonations by Efficient Inhibitors. Gaseous & heterogeneous detonations: Science to applications. Moscow: ENAS Publishers, 1999. pp. 331–336.
6. Fleming J., Williams B., Sheinson R. Suppression Effectiveness of Aerosols: The Effect of Size and Flame Type. Special Publication (NIST SP), National Institute of Standards and Technology. Gaithersburg, 2002. DOI: 10.6028/NIST.SP.984.4
7. Khalikov R.V. The use of combustion inhibitors for volumetric fire extinguishing of gas compressor stations. Rol protivopozharnykh sluzhb v reshenii netraditsionnykh ugroz bezopasnosti: materialy 1-y Mezhdunar. nauch. konf. (The role of fire-fighting services in solving non-traditional security threats: Materials of the 1th international scientific conference). Hanoi: Institut pozharnoy bezopasnosti MOB SRV, 2020 pp. 1535–1540 (in Russ.).
8. Shmakov A.G., Korobeynichev O.P., Shvartsberg V.M., Yakimov S.A., Knyazkov D.A., Komarov V.F., Sakovich G.V. Testing Ogranophosphorus, Organofluorine, and Metal-Containing Compounds and Solid-Propellant Gas-Generating Compositions Doped with Phosphorus-Containing Additives as Effective Fire Suppressants. Fizika goreniya i vzryva = Combustion, Explosion and Shock Waves. 2006. Vol. 42. № 6. pp. 64–73. (In Russ.).
9. Korobeynichev O.P., Shmakov A.G., Chernov A.A., Shvartsberg V.M., Kutsenogiy K.P., Markov V.I. Application of aerosol technology and non-volatile effective fire suppressants for fire-fighting of various types of fires. Interekspo Geo-Sibir = Interexpo GEO-Siberia. 2012. Vol. 2. № 3. pp. 92–101. (In Russ.).
10. Boroday S., Letin A., Shedko S. Experimental study of flame composition and its effect upon fire-retardant structures. Trudy Krylovskogo gosudarstvennogo nauchnogo tsentra = Transactions of the Krylov State Research Centre. 2020. Vol. 2. № 392. pp. 79–88. (In Russ.). DOI: 10.24937/2542-2324-2020-2-392-79-88
11. Puzach S.V, Abakumov E.S. On determining the height of flame area during diffuse combustion of liquid. Pozharovzryvobezopasnost = Fire and Explosion Safety. 2012. № 2. pp. 31–34. (In Russ.).
12. Gottuk D.T., Gott J.E., Williams F.W. Fire Dynamics of Spill Fires: An Experimental Study. Fire Safety Science — Proceedings of the Sixth (6th) International Symposium (IAFSS). Gosport: Interscience Communications, 2000.
13. Vysokomornaya O.V., Markov A.O., Nazarov M.N., Strizhak P.A., Yanov S.R. Numerical study of the impact of water spray in the temperature in the follow movement of «water shell». Izvestiya Tomskogo politekhnicheskogo universiteta. Inzhiniring georesursov = Bulletin of the Tomsk Polytechnic University. Geo assets engineering. 2013. Vol. 322. № 4. pp. 24–31. (In Russ.).
14. Strizhak P.A. Numerical analysis of diffusion and convection heat and mass transfer processes at the moving of water drops through high combustion products. Pozharovzryvobezopasnost = Fire and Explosion Safety. 2013. Vol. 22. № 7. pp. 11–21. (In Russ.).
15. Zhdanova A.O., Kuznetsov G.V., Strizhak P.A. Influence of Water Droplets Distribution in the «Water Shell» on Temperature in Follow Movement. Pozharovzryvobezopasnost = Fire and Explosion Safety. 2013. № 2. pp. 9–17. (In Russ.).
16. Rozentsvayg A.K., Strashinskiy Ch.S. Boiling of droplets of low-boiling of dispersed phase in mode of heterogeneous nucleation. Innovatsionnaya nauka = Innovative Science. 2016. № 11-2. pp. 56–60. (In Russ.).
17. Khasanov R.M., Lishtakov A.A., Chistov Yu.S. Studies of the heat radiation intensity depending on fire source and spill area of flammable liquids and combustible substances. Vestnik tekhnologicheskogo universiteta = Herald of Technological University. 2017. Vol. 20. № 16. pp. 110–112. (In Russ.).
18. Dakhin S.V., Drozdov I.G., Shmatov D.P. To the determination of relative velocity liquid drops in a gas. Vestnik Voronezhskogo gosudarstvennogo tekhnicheskogo universiteta = Bulletin of Voronezh State Technical University. 2013. № 5-1. pp. 86–90. (In Russ.).
19. Markus E.S., Snegirev A.Yu., Kuznetsov E.A., Tanklevskiy L.T., Arakcheev A.V. Simulation of flame spread over discrete fire load. Pozharovzryvobezopasnost = Fire and Explosion Safety. 2019. Vol. 28. № 4. pp. 29–41. (In Russ.). DOI: 10.18322/PVB.2019.28.04.29-41
20. Ogurtsov S., Semichaevskiy S. To the issue about the necessity of reasoning initial data for modeling the turbine oil combustion process. Nauchnyy vestnik: Grazhdanskaya zashchita i pozharnaya bezopasnost = Scientific Bulletin: Civil Protection and Fire Safety. 2016. № 2. pp. 44–48. (In Ukr.).
DOI: 10.24000/0409-2961-2025-1-37-43
Year: 2025
Issue num: January
Keywords : modeling утечки горючие газы volumetric fire extinguishing thermally activated water fire prevention
Authors:
  • Khalikov R.V.
    Lecturer, vokilah@rambler.ru, Academy of GPS of the Ministry of Emergency Situations of Russia, Moscow, Russia
  • Khalikova T.N.
    adjunct, State Fire Academy of EMERCOM of Russia, Moscow, Russian Federation