Radiation Properties of Coal and Thermal Industries Waste



Annotation:

The problem of obtaining environmentally safe materials is particularly relevant when using waste that concentrates natural radionuclides which are dangerous to human health and the environment.

Such radionuclide concentrators include waste from the coal mining and heat power industries. The aim of the work is to determine the radionuclide composition of fractions of coal mining waste and fuel ash-slag and their compliance with the radiation safety standards of the Russian Federation and international radiological indicators. Natural radionuclides 226Ra, 232Th, and 40K were found in the composition of fuel ash-slags and the slag from the coal mining. The content of radionuclides varies by fraction of the waste. The main contribution to the effective specific activity of the waste is made by 226Ra and 232Th.

The largest variation in specific activities by fractions of fuel ash and burnt coal is characteristic of 226Ra. All the investigated wastes belong to the I class of radiation hazard (Cef < 370 Bq/kg) and can be used in construction without limitation. According to the international radiological indicators, the value of the activity utilization index is exceeded for almost all the investigated wastes. The gamma radiation of the burnt dump rocks of the Olkhovatskaya mine (fraction less than 0.63 mm) exceeds the recommended limits in terms of the values of the internal hazard index and gamma index. The values of radium equivalent activity  of 226Ra and the alpha index indicate that the investigated ash-slag and dump rock do not pose a danger of increased emanation of radon and daughter products of its decay into the room air. The concentration of radon entering the room air does not exceed 200 Bq/m3 . The air-absorbed dose rate for the investigated wastes and the annual effective equivalent dose are higher than the world average, respectively: 58 nGy/h and 0.07 mSv, but lower than the value recommended by the IAEA for the population, 1 mSv/y. The excess lifetime carcinogenic risk is higher than the global average: 0.29·10–3 , but below the limit of 0.05 established by the International Commission on Radiation Protection

References:
  1. Sources and effects of ionizing radiation. UNSCEAR 2000 Report to General Assembly, with scientific annexes. Vol. 1: Sources. New York: United Nations, 2000. 654 p.
  2. Pak Yu.N., Pak D.Yu., Ponomaryova M.V., Baizbayev M.B., Zhelayeva N.V. Radioactivity of Coal and Its Combustion Wastes. Coke and Chemistry. 2018. Vol. 61. pp. 188–192. DOI: 10.3103/S1068364X1805006X
  3. Kolo M.T., Khandaker M.U., Amin Y.M., Abdullah W.H.B. Quantification and radiological risk estimation due to the presence of natural radionuclides in Maiganga coal, Nigeria. Plos one. 2016. Vol. 11. Iss. 6. DOI: 10.1371/journal.pone.0158100
  4. Zhou C., Liu G., Cheng S., Fang T., Lam P.K.S. The environmental geochemistry of trace elements and naturally radionuclides in a coal gangue brick-making plant. Scientific Reports. 2014. № 4. pp. 1–9. DOI: 10.1038/srep06221
  5. Zhang N., Liu C. Radiation characteristics of natural gamma-ray from coal and gangue for recognition in top coal caving. Scientific Reports. 2018. № 8. pp. 190–199. DOI: 10.1038/s41598-017-18625-y
  6. Marpaung H., Alfian Z., Raja S.L., Akhyariansyah D., Silalahi D., Simanjuntak C., Harahap R. Analysis and risk assessment of natural radioactivity elements in coal wastes from Medan industrial area. Journal of Physics: Conference Series. 2018. Vol. 1116. Iss. 4. pp. 1–4. DOI: 10.1088/1742-6596/1116/4/042018
  7. Zubova L.G., Zubov A.R., Zubov A.A., Kharlamova A.V., Vorobev S.G., Makarishina Yu.I., Bunyachenko V.V. Waste heaps: monograph. Lugansk: Noulidzh, 2015. 716 p. (In Russ.).
  8. Zubova L.G., Zubov A.R. Assessment of the radioactivity of the rock dumps in the coal mines of PAO Lisichanskugol. Ugol Ukrainy = Coal of Ukraine. 2016. № 2. pp. 59–65. (In Russ.).
  9. Dudu V.P., Mathuthu M., Manjoro M. Assessment of heavy metals and radionuclides in dust fallout in the West Rand mining area of South Africa. Clean Air Journal. 2018. Vol. 28. № 2. pp. 42–52. DOI: 10.17159/2410-972x/2018/v28n2a17
  10. Kolo M.T., Amin Y.M., Khandaker M.U., Abdullah W.H.B. Radionuclide concentrations and excess lifetime cancer risk due to gamma radioactivity in tailing enriched soil around Maiganga coal mine, Northeast Nigeria. International Journal of Radiation Research. 2017. Vol. 15. № 1. pp. 71–80. DOI: 10.18869/acadpub.ijrr.15.1.71
  11. Śleziak M., Duliński M. Suitability of rocks and sediments from Brzeszcze and Silesia coal mines as building materials in terms of radiological hazard. Nukleonika. 2019. Vol. 64. № 2. pp. 65–70. DOI: 10.2478/nuka-2019-0008
  12. Mursa P., Vocheci F., Dumitrescu R.-O., Şufaru L.D.N. Radioactive pollution generated by the electric powers using coal as combustible. International Conference Knowledge-based organization. 2018. Vol. 24. № 3. pp. 59–65. DOI: 10.1515/kbo-2018-0137
  13. Sidorova G.P., Ovseychuk V.A. Determination of specific effficient activity in coals. Gornyy informatsionno-analiticheskiy byulleten = Mining informational and analytical bulletin. 2016. № 8. pp. 369–378. (In Russ.).
  14. Krylov D.A., Sidorova G.P. Radioactivity of coals and ash and slag wastes at coal-fired thermal power plants. Thermal Engineering. 2013. № 60. pp. 239–243. DOI: 10.1134/S0040601513040046
  15. Flues M., Camargo I.M.C., Silva P.S.C., Mazzilli B.P. Radioactivity of coal and ashes from Figueira coal power plant in Brazil. Journal of Radioanalytical and Nuclear Chemistry. 2006. Vol. 270. № 3. pp. 597–602.
  16. Janković M.M., Rajačić M.M., Todorović D.J., Sarap N.B., Nikolić J.D., Pantelić G.K., Krstić M.M. Study of radioactivity in environment around power plants Tent A and Kolubara due to coal burning for 2015. RAD Conference Proceedings. 2016. Vol. 1. pp. 84–89.
  17. Khobotova E., Ignatenko M., Larin V., Kalmykova Yu., Turenko A. Elemental and mineral composition of ash-slag wastes of Slovianska power plant. Chemistry and chemical technology. 2017. Vol. 11. № 3. pp. 378–382. DOI: 10.23939/chcht11.03.378
  18. Khobotova E.B., Kalmykova Yu.S., Ignatenko M.I., Larin V.I. Natural radionuclides of blast furnace slags. Chernye metally = Ferrous metals. 2017. № 1. pp. 23–28. (In Russ.).
  19. SanPiN 2.6.1.2523—09. Radiation Safety Standards NRB-99/2009. Available at: http://docs.cntd.ru/document/902170553 (accessed: April 16, 2020). (In Russ.).
  20. Radiation Safety Standards of Ukraine (NRBU-97). State hygienic standards GGN 6.6.1.-6.5.001.98. Official publication. Kiev, 1998. 159 p. (In Russ.).
  21. Krisyuk E.M. Premises radiation background. Moscow: Energoatomizdat, 1989. 120 p. (In Russ.).
  22. Sokolov I.A. Ways to reduce the levels of ionizing radiation for natural radionuclides in the construction industry. Dnepropetrovsk: PGASA, 2004. 163 p. (In Russ.).
  23. Tufail M. Radium equivalent activity in the light of UNSCEAR report. Environmental monitoring and assessment. 2012. № 184 (9). pp. 5663—5667.
  24. Exposure to radiation from the natural radioactivity in building materials. Report by an NEA Group of Experts. Paris: OECD, 1979. 40 p.
  25. Radiation protection 112. Radiological protection principles concerning the natural radioactivity of building materials. Luxembourg: Directorate-General Environment, 1999. 18 p.
  26. Sources and effects of ionizing radiation. UNSCEAR 2008 Report to the General Assembly, with scientific annexes. Vol. 1. New York: United Nations, 2010. 683 p.
  27. 1990 Recommendations of the International Commission on radiological protection. Annals of the ICRP. 1991. Vol. 21. Iss. 1–3. pp. 1–201.
  28. Radiation protection and safety of radiation sources: international basic safety codes. Vena: MAGATE, 2015. 484 p. (In Russ.).
  29. Khobotova E.B., Grayvoronskaya I.V., Kalyuzhnaya Yu.S., Ignatenko M.I. Radiation Safety of Concrete. Bezopasnost truda v promyshlennosti = Occupational Safety in Industry. 2019. № 8. pp. 50‒56. (In Russ.). DOI: 10.24000/0409-2961-2019-8-50-56
DOI: 10.24000/0409-2961-2020-8-60-67
Year: 2020
Issue num: August
Keywords : effective specific activity radon emanation radionuclides fuel slags coal mining waste class of radiation hazard radiation hazard indices radiation doses
Authors:
    ;
  • Khobotova E.B.
    Dr. Sci. (Chem.), Prof., elinahobotova@gmail.com Kharkov National Auto-Road University, Kharkov, Ukraine
  • Ignatenko M.I.
    Cand. Sci. (Eng.), Assoc. Prof. Kharkov National Auto-Road University, Kharkov, Ukraine
  • Belichenko E.A.
    Cand. Sci. (Eng.), Senior Research Assistant Kharkov National Automobile and Highway University, Kharkiv, Ukraine
  • Ponikarovskaya S.V.
    Senior Lecturer Kharkov National Automobile and Highway University, Kharkiv, Ukraine